Hydrogen Powered Vehicles 2003


The trouble with today's cars is that they still put out a lot of pollution, and use up fossil fuels. One day, we have to run out of fossil fuels. People have been talking about running cars on water for ages. Unfortunately, most of the time, these people are crackpots. But there is a certain amount of truth in what they say.

Now I know that trying to predict the future is hard, but I reckon that an electric car, powered by a fuel cell running on hydrogen, could be a goer! If you remember back to your chemistry classes at school, water is H2O. In other words, a molecule of water is made up of two atoms of hydrogen, and one atom of oxygen. If you use energy, and pass electricity through water, you can split water into hydrogen and oxygen. And you can run this reaction backwards, and combine hydrogen and oxygen to give you water and energy. (In fact, the word, "hydrogen", means "maker of water" in the original Greek language.)

 


There are two main ways that you can burn hydrogen with oxygen, to give you water, and energy.

The first way is that you can burn hydrogen in a modified car engine. Two companies, BMW and Mazda, are working on this. The engine works fine, but with about 20% less power - which is pretty reasonable, considering that we have been working on the petrol engine for a century or so. When you burn hydrogen in an engine, you get mostly water coming out of the tailpipe. You also get small amounts of oxides of nitrogen (from the nitrogen in the air), and even smaller amount of hydrocarbons (from traces of the lubricants in the combustion chambers of the engine). Even so, a hydrogen-powered car is much less polluting than a petrol-powered car. Of course, you use a normal gearbox and diff.

The second way to use hydrogen to run your car is in an electric car. Mercedes-Benz have been using a strange device called a fuel cell, which has been around since 1839.

 


A fuel cell is very similar to a battery. Both a fuel cell and a battery turn a chemical reaction into electrical energy. But a battery is sealed, and when the "goodness" in the chemicals is used up, the battery is flat. A fuel cell is like a battery, but with one important different difference - you can pump in the chemicals indefinitely. Fuel cells take in hydrogen and oxygen, and give off pure drinking water, and electricity. You use the electricity to run electric motors.

Fuel cells are up to 80% efficient. They will get two or three times more energy out of hydrogen, than will a modified car engine. This is because the internal combustion engine has a stage where you generate a lot of heat - and this is where a lot of energy is wasted, and where the efficiency goes right down.

The real problem with today's electric cars is that our battery technology is pathetic. The battery pack in today's best electric car, the EV-1, gives great acceleration, but a range of less than 100 kilometres. But if you use a fuel cell instead of a battery, you suddenly get an electric car with very low pollution, and good range and performance.

There are two main ways to store hydrogen in your car-of-the-future. First, you can squash it and turn it into a liquid - but the container has to be very strong and heavy, and you have to insulate it to keep it at a temperature of about 260oC below zero.

The second way is to shove the gas into a metal, such as magnesium, and it will squash into the spaces between the magnesium atoms. It sounds unbelievable, but you can actually store more hydrogen inside a metal, than you can as a liquid. Nelly Rodriguez and her fellow scientists at Northeastern University in Boston claim that they can do even better. They used incredibly thin sheets of graphite only one third of a billionth of a metre apart, and they reckon that they can store 30 litres of hydrogen on a single gram of graphite, which works out to an amazing 8,000 kilometres per tank, with your hydrogen-powered car.

Either way, you can fill your tank in under three minutes - which is not much different from filling up with petrol.

One problem with hydrogen is the bad public relations angle - most of us have heard of hydrogen bombs, and seen the dramatic footage of the hydrogen-filled Hindenberg airship exploding in 1937. But hydrogen can be stored safely - in a series of tests on a tank of liquid hydrogen, BMW played flames at 900oC on it for 70 minutes, punched holes into it, and even squashed it until it broke. Sometimes the hydrogen leaked out, and sometimes it caught alight, but it never exploded.

At the moment, in the USA alone, there's about $200 billion invested in shifting and storing petrol, and it would take an enormous effort to start dealing with hydrogen.BMW has 15 of the 750hL sedans participating in its Clean Energy road show.

Combined, the cars have traveled more than 63,000 miles, (100,000 kilometers). But with just one place to "fill up," hydrogen cars are now practical only in and around Bavaria, near the Munich filling station. Right now, the car's range is limiting: just 217.5 miles (350 km). The hydrogen sedans are not on the market yet, but BMW is already considering ways to broaden their sales possibilities.

One of the company's goals is a hydrogen filling station in every European capital by 2005. Mass acceptance? Years of promoting mass transit have not ended love affairs with the car in any industrialized country. So the mindset now in some transportation circles and smoggy city governments is to at least get drivers into low- or non-polluting vehicles. "I won't argue about whether this will happen in 30 years, 40 years, or 50 years ... but it WILL happen," says Professor Ulrich Wagner of Munich's Ludwig Maximilian University. Wagner says car and energy companies, as well as local and national governments, must work on a common path to make hydrogen-fueled cars a reality. "We need better storage systems, more efficient storage systems, and we need a certain infrastructure in order to get started," said Wagner, who teaches courses on renewable energy.

While hydrogen is the lightest element, it has some tricky characteristics. It only becomes liquid at dramatically low temperatures -- -423 degrees Fahrenheit (-253 degrees Celsius). To keep the fuel that cold, fuel tanks in the BMW cars are made of 70 layers of fiberglass and aluminum. Hydrogen fuel is now created through an electrolysis process. Electrodes are stimulated by light, which split water molecules into hydrogen and oxygen.

What about safety?

Safety issues are a major concern for a fuel that's often perceived as more dangerous than others. While hydrogen itself played no part in either catastrophe, it was the fuel in both the Hindenburg and the Challenger. Wagner says consumers should not fear a hydrogen-powered vehicle. "Of course there is some risk, but it is comparable to the risk we have with conventional automotive fuels," he said. BMW conducted numerous crash tests to see what would happen if the hydrogen tank was punctured or damaged.

Their engineers report the liquid hydrogen dissipated harmlessly into the air. What, if anything, will provide a kick-start for hydrogen or other alternative fuels? It could be economic, with the cost of gasoline now topping $4 a gallon in much of Europe. Or it could be political, like California's tough emissions standards. Or, in clogged cities that already have serious smog problems, health issues could tip the scale toward developing cleaner energy sooner, rather than later. "You start with fleet and other specialized applications, like airport buses, or transporting VIP's," says Jim Ohi, a hydrogen expert at the National Renewable Energy Laboratory in Colorado. "In the U.S. there are also federal programs, clean city programs, that mandate alternative vehicles for part of government fleets." Ohi says there's a reason "oil companies" are now referring to themselves as "energy companies: "They're feeling the pressure to study zero-emission fuels, even if it may be decades before they make any money with it." "We have problems with our C02 emissions concerning the climate," says BMW's Pehr. "Especially with big cities. Look at Mexico City (Mexico), Athens (Greece), or Los Angeles (California).

Hydro supporters feel we can solve these problems just by a new energy carrier in the future." A few pilot projects using hydrogen fuel exist in the United States. Several are in California, where residents are more in tune with energy alternatives such as solar and wind power for electricity generation. And because of recent rolling blackouts and enormous increases in electric costs, perhaps more open to looking beyond current technology.

The world probably won't get a hydrogen energy economy in the near future - but we might further down the line, as we begin to run out of fossil fuels.

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